Five diastereomers of ruthenium(II) complexes based on quinolinophaneoxazoline ligands were investigated by vibrational circular dichroism (VCD) in the mid-IR and CH stretching regions. Diastereomers differ in three sources of chirality: the planar chirality of the quinolinophane moiety, the central chirality of an asymmetric carbon atom of the oxazoline ring, and the chirality of the ruthenium atom. VCD, allied to DFT calculations, has been found to be effective in disentangling the various forms of chirality. In particular, a VCD band is identified in the CH stretching region directly connected to the chirality of the metal. The analysis of the calculated VCD spectra is carried out by partitioning the complexes into fragments. The anharmonic analysis is also performed with a recently proposed reduced-dimensionality approach: such treatment is particularly important when examining spectroscopic regions highly perturbed by resonances, like the CH stretching region.Five diastereomeric Ru(II) complexes possessing three types of chirality were investigated by VCD in the mid-IR and CH-stretching regions and by advanced DFT calculations, involving fragment partitioning and reduced anharmonic approach, limited to the CH-stretching region. The combined effort allowed to identify VCD signals for the different sources of chirality. image
Mid‐IR and CH stretching vibrational circular dichroism spectroscopy to distinguish various sources of chirality: The case of quinophaneoxazoline based ruthenium(II) complexes
Fusè, Marco;Mazzeo, Giuseppe;Abbate, Sergio;Longhi, Giovanna
2024-01-01
Abstract
Five diastereomers of ruthenium(II) complexes based on quinolinophaneoxazoline ligands were investigated by vibrational circular dichroism (VCD) in the mid-IR and CH stretching regions. Diastereomers differ in three sources of chirality: the planar chirality of the quinolinophane moiety, the central chirality of an asymmetric carbon atom of the oxazoline ring, and the chirality of the ruthenium atom. VCD, allied to DFT calculations, has been found to be effective in disentangling the various forms of chirality. In particular, a VCD band is identified in the CH stretching region directly connected to the chirality of the metal. The analysis of the calculated VCD spectra is carried out by partitioning the complexes into fragments. The anharmonic analysis is also performed with a recently proposed reduced-dimensionality approach: such treatment is particularly important when examining spectroscopic regions highly perturbed by resonances, like the CH stretching region.Five diastereomeric Ru(II) complexes possessing three types of chirality were investigated by VCD in the mid-IR and CH-stretching regions and by advanced DFT calculations, involving fragment partitioning and reduced anharmonic approach, limited to the CH-stretching region. The combined effort allowed to identify VCD signals for the different sources of chirality. imageFile | Dimensione | Formato | |
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Chirality - 2024 - Fusè - Mid‐IR and CH stretching vibrational circular dichroism spectroscopy to distinguish various (2).pdf
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