Confinement within supramolecular systems is the leading technology to finely tune guest functional properties. In this communication we report the synthesis of a chiral supramolecular cage able to bias the helicity of a perfluorinated carbon chain hosted within the cage. We monitor the phenomenon of chiral induction by Vibrational Circular Dichroism (VCD) experiments complemented by DFT calculations over the possible conformers.
Helicity control of a perfluorinated carbon chain within a chiral supramolecular cage monitored by VCD
Mazzeo, Giuseppe;Abbate, Sergio;Longhi, Giovanna
;
2022-01-01
Abstract
Confinement within supramolecular systems is the leading technology to finely tune guest functional properties. In this communication we report the synthesis of a chiral supramolecular cage able to bias the helicity of a perfluorinated carbon chain hosted within the cage. We monitor the phenomenon of chiral induction by Vibrational Circular Dichroism (VCD) experiments complemented by DFT calculations over the possible conformers.File in questo prodotto:
| File | Dimensione | Formato | |
|---|---|---|---|
|
d1cc06861j.pdf
accesso aperto
Tipologia:
Full Text
Licenza:
Copyright dell'editore
Dimensione
2.11 MB
Formato
Adobe PDF
|
2.11 MB | Adobe PDF | Visualizza/Apri |
I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
