Reasonable structural models are proposed for the Cu complexes of two intercalated compounds of α-Zr(HPO4)2·H2O (α-ZrP): one with 1,10-phenanthroline (A) and the other with 2,2′-bipyridyl (B). The models are derived from considerations of the unit-cell geometry changes undergone by α-ZrP upon insertion of, first, the organic molecules and then copper, in accordance with a set of general criteria of structural analysis called the "comparison method.
Diffraction and XPS studies of Cu complexes of intercalated compounds of α-zirconium phosphate. I: Derivation of structural models from powder diffraction data
DEPERO, Laura Eleonora;ZOCCHI, Marcello;
1994-01-01
Abstract
Reasonable structural models are proposed for the Cu complexes of two intercalated compounds of α-Zr(HPO4)2·H2O (α-ZrP): one with 1,10-phenanthroline (A) and the other with 2,2′-bipyridyl (B). The models are derived from considerations of the unit-cell geometry changes undergone by α-ZrP upon insertion of, first, the organic molecules and then copper, in accordance with a set of general criteria of structural analysis called the "comparison method.File in questo prodotto:
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