Journal of Solid State Chemistry Volume 104, Issue 2, June 1993, Pages 209-214 The Crystal Structure of the Cesium Molybdenum Bronze CS0.14MoO3 (Article) Depero, L.E., Zocchi, M., Zocchi, F., Demartin, F. Dipartimento di Ingegneria Meccanica dell'Università, Via Branze, 25123 Brescia, Italy; IMAI-CNR Area della Ricerca di Roma, 00016 Monterotondo Stazione, Rome, Italy and Istituto di Chimica Strutturistica Inorganica dell'Università degli Studi, Via G. Venezian 21, 20133, Milan, Italy Abstract The crystal of the title compound is hexagonal, space group P 63/m, with a = 10.620(9), c = 3.722(2) Å, and Z = 6. Couples of MoO6 distorted octahedra, linked by edges, constitute, by repetitive edge sharing along the c axis, ribbons kept together in bundles by lateral corner sharing. These bundles, by being packed together, generate tunnels where delocalized Cs atoms are inserted. The results confirmed the previously found correlation between the Mo oxidation state and the distortion of the coordination "octahedra" and allow one to extend the correlation to the possible conduction properties of the title compound and to those of structurally related oxides and bronzes. © 1993 Academic Press. All rights reserved. Reaxys Database Information | ISSN: 00224596 CODEN: JSSCBSource Type: Journal Original language: English DOI: 10.1006/jssc.1993.1155Document Type: Article Depero, L.E.; Dipartimento di Ingegneria Meccanica dell'Università, Via Branze, 25123 Brescia, Italy; IMAI-CNR Area della Ricerca di Roma, 00016 Monterotondo Stazione, Rome, Italy and Istituto di Chimica Strutturistica Inorganica dell'Università degli Studi, Via G. Venezian 21, 20133, Milan, Italy, © Copyright 2008 Elsevier B.V., All rights reserved.
The Crystal Structure of the Cesium Molybdenum Bronze CS0.14MoO3
DEPERO, Laura Eleonora;ZOCCHI, Marcello;
1993-01-01
Abstract
Journal of Solid State Chemistry Volume 104, Issue 2, June 1993, Pages 209-214 The Crystal Structure of the Cesium Molybdenum Bronze CS0.14MoO3 (Article) Depero, L.E., Zocchi, M., Zocchi, F., Demartin, F. Dipartimento di Ingegneria Meccanica dell'Università, Via Branze, 25123 Brescia, Italy; IMAI-CNR Area della Ricerca di Roma, 00016 Monterotondo Stazione, Rome, Italy and Istituto di Chimica Strutturistica Inorganica dell'Università degli Studi, Via G. Venezian 21, 20133, Milan, Italy Abstract The crystal of the title compound is hexagonal, space group P 63/m, with a = 10.620(9), c = 3.722(2) Å, and Z = 6. Couples of MoO6 distorted octahedra, linked by edges, constitute, by repetitive edge sharing along the c axis, ribbons kept together in bundles by lateral corner sharing. These bundles, by being packed together, generate tunnels where delocalized Cs atoms are inserted. The results confirmed the previously found correlation between the Mo oxidation state and the distortion of the coordination "octahedra" and allow one to extend the correlation to the possible conduction properties of the title compound and to those of structurally related oxides and bronzes. © 1993 Academic Press. All rights reserved. Reaxys Database Information | ISSN: 00224596 CODEN: JSSCBSource Type: Journal Original language: English DOI: 10.1006/jssc.1993.1155Document Type: Article Depero, L.E.; Dipartimento di Ingegneria Meccanica dell'Università, Via Branze, 25123 Brescia, Italy; IMAI-CNR Area della Ricerca di Roma, 00016 Monterotondo Stazione, Rome, Italy and Istituto di Chimica Strutturistica Inorganica dell'Università degli Studi, Via G. Venezian 21, 20133, Milan, Italy, © Copyright 2008 Elsevier B.V., All rights reserved.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
