We report the structural characterisation of La1-xNaxMnO3+delta thin films deposited by Rf-magnetron sputtering onto SrTiO3 (100) single crystal substrates. In particular, we focussed our attention on a series of samples annealed at different pO(2), ranging from 1 to 10(-6) atm. XRD and microRaman data show an expansion of the perovskite lattice for samples annealed in reducing conditions. This results agree with general manganite gas-solid equilibrium involving the formation of Mn4+ as the oxygen content increases. For pO(2) <10(-6) atm the structure rearranges because of the increasing the oxygen vacancies and the volume of the unit cell shrinks.
Sodium doped lanthanum manganites thin films: Influence of the oxygen content on the structural parameters
ALESSANDRI, Ivano;BONTEMPI, Elza;DEPERO, Laura Eleonora
2004-01-01
Abstract
We report the structural characterisation of La1-xNaxMnO3+delta thin films deposited by Rf-magnetron sputtering onto SrTiO3 (100) single crystal substrates. In particular, we focussed our attention on a series of samples annealed at different pO(2), ranging from 1 to 10(-6) atm. XRD and microRaman data show an expansion of the perovskite lattice for samples annealed in reducing conditions. This results agree with general manganite gas-solid equilibrium involving the formation of Mn4+ as the oxygen content increases. For pO(2) <10(-6) atm the structure rearranges because of the increasing the oxygen vacancies and the volume of the unit cell shrinks.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
