Synthesis of Nb-containing titania nanotubular arrays at room temperature by electrochemical anodization is reported. Crystallization of pure and Nb-doped TiO2 nanotubes was carried out by post-growth annealing at 400 °C. The morphology of the tubes obtained was characterized by scanning electron microscopy (SEM). Crystal structure and composition of tubes were investigated by glancing incidence x-ray diffraction (GIXRD) and total reflection x-ray fluorescence (TXRF). For the first time gas sensing characteristics of Nb-doped TiO2 nanotubes were investigated and compared to those of undoped nanotubes. The functional properties of nanotubular arrays towards CO, H2, NO2, ethanol and acetone were tested in a wide range of operating temperature. The introduction of Nb largely improves conductivity and enhances gas sensing performances of TiO2 nanotubes.

Fabrication and investigation of gas sensing properties of Nb-doped TiO2 nanotubular arrays

GALSTYAN, Vardan;COMINI, Elisabetta;FAGLIA, Guido;VOMIERO, Alberto;BORGESE, Laura;BONTEMPI, Elza;SBERVEGLIERI, Giorgio
2012-01-01

Abstract

Synthesis of Nb-containing titania nanotubular arrays at room temperature by electrochemical anodization is reported. Crystallization of pure and Nb-doped TiO2 nanotubes was carried out by post-growth annealing at 400 °C. The morphology of the tubes obtained was characterized by scanning electron microscopy (SEM). Crystal structure and composition of tubes were investigated by glancing incidence x-ray diffraction (GIXRD) and total reflection x-ray fluorescence (TXRF). For the first time gas sensing characteristics of Nb-doped TiO2 nanotubes were investigated and compared to those of undoped nanotubes. The functional properties of nanotubular arrays towards CO, H2, NO2, ethanol and acetone were tested in a wide range of operating temperature. The introduction of Nb largely improves conductivity and enhances gas sensing performances of TiO2 nanotubes.
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11379/158482
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