Vibrational circular dichroism spectra allow one to assign the absolute configuration and to monitor the conformational equilibria related to CF3⋅⋅⋅OH hydrogen bonding of [2.2]paracyclophane with an external stereogenic carbon atom bearing CF3, OH and H
Vibrational Circular Dichroism (VCD): a Valuable Tool for Conformational Analysis and Absolute Configuration Assignment of Chiral 1-([2.2.]Paracyclophan-4-yl)-2,2,2-trifluoroethanol
ABBATE, Sergio;LEBON, France;LONGHI, Giovanna;GANGEMI, Roberto;
2011-01-01
Abstract
Vibrational circular dichroism spectra allow one to assign the absolute configuration and to monitor the conformational equilibria related to CF3⋅⋅⋅OH hydrogen bonding of [2.2]paracyclophane with an external stereogenic carbon atom bearing CF3, OH and HFile in questo prodotto:
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