Doped Ceria Catalysts for NOx Storage and Reduction

The new Euro 7 protocol, proposed by the Commission on 26th October 2022, concerning emissions of leanburn engines, presents a need for further optimisation of existing after-treatment technologies. It reveals a 35% reduction to the NOx emission limit for cars and vans, compared to Euro 6 . A well-known technology employed to reduce NOx to clean emissions in light-duty vehicles is the Lean NOx Trap (LNT). LNTs employ catalysts consisting of PGMs supported on ceria (CeO2) or other mixed oxides. Ceria’s redox property makes it an attractive selection, as well as its ability to store NOx at low temp (<300 ˚C), especially when Pt is present. Storage properties of ceria can be further enhanced by doping. Dopants reportedly allow ceria to function better at low temperature (<300 ˚C), and to reduce the PGM loading required to achieve the same conversion efficiencies. The RE metals Sm, Pr and Nd have been employed as dopants on CeO2 for LNT applications to increase surface oxygen content, oxygen vacancies, defect densities, and cause changes to the Pt-ceria interaction. These structural changes can allow for higher NSC during lean operation and enhanced activation during rich purge. Sm, Pr and Nd doped catalysts (10 wt.%) were synthesised on a range of ceria based catalysts with different Pt loadings (0-1 wt.%). Morphological changes observed through dopant addition has been investigated and related to catalytic performance increases."