Organic conducting polymers, particularly poly(3,4-ethylenedioxythiophene):polystyrene sulfonate (PEDOT:PSS), are emerging as versatile candidates for advanced optoelectronic applications due to their mechanical flexibility, ease of fabrication, and tunable optoelectronic properties. This work explores two significant innovations using PEDOT:PSS: i) the development of ionically tunable gradient-index (GRIN) materials through electrochemical modulation and ii) the characterization of their sub-picosecond nonlinear optical response. The ion-injection process allows for dynamic, reversible tuning of the polymer's refractive index, enabling adaptive optical components such as beam steerers and optical interconnects. Additionally, the films exhibit ultrafast nonlinear behavior, with a nonlinear susceptibility significantly higher than traditional transparent conducting oxides, making them ideal for low-power, high-speed photonic applications. These findings position PEDOT:PSS as a promising platform for integrated, multifunctional photonic devices.
From Gradient Index to Nonlinear Effects: Tailored Optics in Organic Polymer Systems
Franceschini P.;Demartis V. M.;De Ceglia D.;Carletti L.;Menshikov E.;Alessandri I.;Torricelli F.;Vincenti M. A.
2025-01-01
Abstract
Organic conducting polymers, particularly poly(3,4-ethylenedioxythiophene):polystyrene sulfonate (PEDOT:PSS), are emerging as versatile candidates for advanced optoelectronic applications due to their mechanical flexibility, ease of fabrication, and tunable optoelectronic properties. This work explores two significant innovations using PEDOT:PSS: i) the development of ionically tunable gradient-index (GRIN) materials through electrochemical modulation and ii) the characterization of their sub-picosecond nonlinear optical response. The ion-injection process allows for dynamic, reversible tuning of the polymer's refractive index, enabling adaptive optical components such as beam steerers and optical interconnects. Additionally, the films exhibit ultrafast nonlinear behavior, with a nonlinear susceptibility significantly higher than traditional transparent conducting oxides, making them ideal for low-power, high-speed photonic applications. These findings position PEDOT:PSS as a promising platform for integrated, multifunctional photonic devices.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
